Methyl tunnelling of adsorbed methoxy on an alumina catalyst

Methyl tunnelling of adsorbed methoxy on alumina catalysts.

The aim of this paper is to investigate whether the methyl group of the adsorbed methoxy intermediate on industrial grade alumina catalysts undergoes rotational tunnelling on the wavenumber energy scale. The data show that this is clearly the case for a fraction of the methyl groups and potentially allows the subtle intermolecular interactions between adsorbed species and catalyst to be probed ...

Infrared Study of the Surface Species Formed by Sequential Chemical Vapor Deposition of Trimethylaluminum and Methanol on a Hydroxylated Alumina Surface

Infrared spectroscopy is used to follow the chemical changes, as a function of temperature, after sequentially adsorbing trimethylaluminum (TMA) and methanol on hydroxylated alumina. Deuterium-labeled methanol is used to distinguish between the chemistry of methyl and methoxy species. To differentiate between methanol adsorbed on TMA-derived sites and on alumina, the adsorption of methanol is s...

Abatement of Benzyl Alcohol and Methyl Ethyl Ketone (MEK) from Polluted Air Over Nanostructured Mn -Supported Alumina Catalyst

Highly efficient catalyst for removal of heavy metal ions modified by a novel Schiff base ligand

An alomina-based nano adsorbent was prepared by modification of the external surface of γ-alumina (γ-Al2O3) nanoparticles with functional groups of a new Schiff base 4-[(2-hydroxy-3-methoxy-benzylidene)-amino]-5-methyl-2,4-dihydro-[1,2.4]triazole-3-thione] “L”. In order to the removal of Cr(VI) from aqueous solutions, we used the reaction of the sodium dodecyl sulfate coated nano-alumina with L...

The development of a new generation of methyl chloride synthesis catalyst.

In previous work by the authors, aspects of the surface chemistry connected with methyl chloride synthesis over an η-alumina catalyst have been examined. This communication considers a role for Group 1 metal salts to modify the catalytic performance of the well characterised η-alumina catalyst. Firstly, based on a previously postulated mechanism for the reaction of methanol on η-alumina, a mech...